Tang Kai, Farooqi Sidra Anis, Wang Xianfu, Yan Chenglin
Soochow Institute for Energy and Materials Innovations, College of Energy, Soochow University, Suzhou, 215006, PR China.
Jiangsu Provincial Key Laboratory for Advanced Carbon Materials, and Wearable Energy Technologies, Soochow University, Suzhou, 215006, PR China.
ChemSusChem. 2019 Feb 21;12(4):755-771. doi: 10.1002/cssc.201801860. Epub 2019 Feb 7.
Diminishing fossil-fuel resources and a rise in energy demands has required the pursuit of sustainable and rechargeable energy-storage materials, including batteries and supercapacitors, the electrochemical properties of which depend largely on the electrode materials. In recent decades, numerous electrode materials with excellent electrochemical energy-storage capabilities, long life spans, and environmentally acceptable qualities have been developed. Among existing materials, molybdenum oxides containing MoO and MoO , as well as their composites, are very fascinating contenders for competent energy-storage devices because of their exceptional physicochemical properties, such as thermal stability, high theoretical capability, and mechanical strength. This Minireview mainly focuses on the latest progress for the use of molybdenum oxides as electrode materials for lithium-ion batteries; sodium-ion batteries; and other novel batteries, such as lithium-sulfur batteries, lithium-oxygen batteries, and newly developed hydrogen-ion batteries, with a focus on studies of the reaction mechanism, design of the electrode structures, and improvement of the electrochemical properties.
化石燃料资源的减少和能源需求的增加,促使人们寻求可持续和可充电的储能材料,包括电池和超级电容器,其电化学性能在很大程度上取决于电极材料。近几十年来,人们已经开发出了许多具有优异电化学储能能力、长寿命和环境友好特性的电极材料。在现有材料中,含有MoO和MoO的氧化钼及其复合材料,因其具有出色的物理化学性质,如热稳定性、高理论容量和机械强度,是极具竞争力的储能器件材料。本综述主要关注氧化钼作为锂离子电池、钠离子电池以及其他新型电池(如锂硫电池、锂氧电池和新开发的氢离子电池)电极材料的最新进展,重点是反应机理研究、电极结构设计以及电化学性能的改善。