通过硫代羰基加成-开环（TARO）聚合制备可降解乙烯基共聚物。
Degradable vinyl copolymers through thiocarbonyl addition-ring-opening (TARO) polymerization.
机构信息
Department of Chemistry, University of Surrey, Guildford, Surrey, GU2 7XH, UK.
出版信息
Chem Commun (Camb). 2018 Dec 18;55(1):55-58. doi: 10.1039/c8cc08287a.
PMID:30484445
Abstract
The radical copolymerization of the thionolactone dibenzo[c,e]oxepane-5-thione with acrylates, acrylonitrile, and N,N-dimethylacrylamide afforded copolymers containing a controllable amount of backbone thioesters which could be selectively cleaved. The process is compatible with RAFT polymerization and promising for the development of advanced degradable polymers.
摘要
噻吩并[C，E]氧杂环戊烯-5-硫酮与丙烯酸酯、丙烯腈和 N，N-二甲基丙烯酰胺的自由基共聚，得到了含有可控数量的主链硫酯的共聚物，这些硫酯可以被选择性地切断。该过程与 RAFT 聚合兼容，为开发先进的可降解聚合物提供了广阔的前景。
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