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大气压等离子体增强化学气相沉积法对铟镓锌氧化物进行氢等离子体处理的研究

Study of Hydrogen Plasma Treatment on InGaZnO with Atmospheric Pressure-Plasma Enhanced Chemical Vapor Deposition.

作者信息

Wu Chien-Hung, Chang Kow-Ming, Chen Yi-Ming, Zhang Yu-Xin, Tan Yu-Hsuan

机构信息

Department of Electronics Engineering, Chung Hua University, Hsinchu, Taiwan, 30012, R.O.C.

Department of Electronics Engineering, National Chiao Tung University, Hsinchu, Taiwan, 30010, R.O.C.

出版信息

J Nanosci Nanotechnol. 2019 Apr 1;19(4):2310-2313. doi: 10.1166/jnn.2019.15997.

Abstract

In the past few years, thin film transistors have a wide range of applications on display technology, material selection and quality for its active layer is critical for device performance. Traditional amorphous silicon (a-Si) silicon has a lot of advantages such as good productivity, short process and low-cost. It also has a lot of shortcomings on these applications on TFTs such as photosensitivity, light degradation, and opacity, etc. The dispute of the material based on a-Si:H as an active layer in TFT is low field effect mobility (1 cm²/V·S) (M. Shur and M. Hack, 55, 3831 (1984)), photo sensitivity (low band gap about 1.7 V) and high deposition temperature (400 °C) (M. Shur, et al., 66, 3371 (1989); K. Khakzar and E. H. Lueder, 39, 1438 (1992)). Amorphous In-Ga-Zn-O (IGZO) had attracted attention that compared with the conventional a-Si:H, due to its good properties of simultaneously high/low conductivity with high visual transparency via doping level. Oxide-based semiconductors, such as ZnO (G. Adamopoulos, et al., 95, 133507-3 (2009); H.-C. Cheng, et al., 90, 012113-3 (2007)) and IGZO (C. J. Chiu, et al., 31, 1245 (2010); L. Linfeng and P. Junbiao, 58, 1452 (2011)) have been reported for the active channel layer. These oxide-based materials offer good electrical properties and high transparency for thin film transistors, its high transmittance can be applied to fabricate the full transparent TFT on flexible substrate. With hydrogen plasma treatment on a-IGZO produced by atmospheric pressure-plasma enhanced chemical vapor deposition (AP-PECVD), the material characteristics of a-IGZO is studied.

摘要

在过去几年中,薄膜晶体管在显示技术方面有广泛应用,其有源层的材料选择和质量对器件性能至关重要。传统的非晶硅(a-Si)有许多优点,如生产率高、工艺短和成本低。但在薄膜晶体管的这些应用中它也有很多缺点,如光敏性、光致降解和不透明度等。基于a-Si:H作为薄膜晶体管有源层的材料存在争议,其场效应迁移率较低(约1 cm²/V·S)(M. 舒尔和M. 哈克,《应用物理快报》55卷,3831页(1984年)),有光敏性(带隙约1.7 V较低)且沉积温度较高(约400 °C)(M. 舒尔等人,《应用物理快报》66卷,3371页(1989年);K. 哈克扎尔和E. H. 吕德,《应用物理快报》39卷,1438页(1992年))。非晶铟镓锌氧化物(IGZO)已引起关注,与传统的a-Si:H相比,它通过掺杂水平具有同时高/低导电性和高视觉透明度的良好特性。基于氧化物的半导体,如氧化锌(G. 阿达莫普洛斯等人,《应用物理快报》95卷,133507 - 3页(2009年);H.-C. 程等人,《应用物理快报》90卷,012113 - 3页(2007年))和IGZO(C. J. 邱等人,《应用物理快报》31卷,1245页(2010年);L. 林峰和P. 俊彪,《应用物理快报》58卷,1452页(2011年))已被报道用于有源沟道层。这些基于氧化物的材料为薄膜晶体管提供了良好的电学性能和高透明度,其高透射率可应用于在柔性基板上制造全透明薄膜晶体管。通过对大气压等离子体增强化学气相沉积(AP - PECVD)制备的a - IGZO进行氢等离子体处理,研究了a - IGZO的材料特性。

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