形态对单个胶体纳米板的闪烁机制和激子精细结构的影响。

Influence of morphology on the blinking mechanisms and the excitonic fine structure of single colloidal nanoplatelets.

机构信息

Center for Integrated Nanotechnologies, Material Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.

出版信息

Nanoscale. 2018 Dec 13;10(48):22861-22870. doi: 10.1039/c8nr06234j.

Abstract

Colloidal semiconductor nanoplatelets with a similar electronic structure as quantum wells have recently emerged as exciting materials for optoelectronic applications. Here we investigate how morphology affects important photoluminescence properties of single CdSe and core/shell CdSe/CdZnS nanoplatelets. By analyzing photoluminescence intensity-lifetime correlation and second-order photon correlation results, we demonstrate that, irrespective of the morphology, Auger recombination plays only a minor role in dictating the blinking behavior of the nanoplatelets. We find that a rough shell induces additional nonradiative channels presumably related to defects or traps of an imperfect shell. Furthermore, polarization-resolved spectroscopy analysis reveals exciton fine-structure splitting of the order of several tens of meV in rough-shell nanoplatelets at room temperature, which is attributed to exciton localization and is substantiated by theoretical calculations taking into account the nanoplatelet shape and electron-hole exchange interaction.

摘要

具有类似量子阱电子结构的胶体半导体纳米板最近成为光电应用中令人兴奋的材料。在这里,我们研究了形态如何影响单个 CdSe 和核/壳 CdSe/CdZnS 纳米板的重要光致发光性质。通过分析光致发光强度-寿命相关和二阶光子相关结果,我们证明,无论形态如何,俄歇复合在决定纳米板的闪烁行为方面只起很小的作用。我们发现粗糙的壳层会诱导额外的非辐射通道,这可能与不完美壳层的缺陷或陷阱有关。此外,偏振分辨光谱分析表明,在室温下,粗糙壳层纳米板中存在几十毫伏数量级的激子精细结构分裂,这归因于激子局域化,并通过考虑纳米板形状和电子-空穴交换相互作用的理论计算得到证实。

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