Department of Environmental Science and Engineering, Huaqiao University, Xiamen 361021, PR China.
Department of Environmental Science and Engineering, Huaqiao University, Xiamen 361021, PR China.
Bioresour Technol. 2019 Feb;274:225-231. doi: 10.1016/j.biortech.2018.11.092. Epub 2018 Nov 26.
This study developed an integrated approach for electric energy harvest/resource reuse from waste activated sludge (WAS) pretreated by enzymolysis based on anaerobic fermentation and microbial fuel cells (MFCs). WAS solubilization by the 3-h enzymatic pretreatment (a blend of hydrolytic enzymes caused over 5300 mg/L soluble COD release) prompted volatile fatty acid (VFA) production with 3580 mg COD/L after 10-d fermentation. After solid-liquid separation, fermentation liquid with high VFA content was fed into MFCs for electric energy production, while solid residues were used for making building materials (such as blended cements). Results showed that the electricity conversion efficiency of fermentation liquid (VFA) reached 1.254 kW h/kg COD with over 90% organics removal and solid residues could be consumed potentially as qualified substitutes for producing cements. As such, this study may provide some new thinking on future WAS management towards electricity harvest/resource reuse with zero secondary wastes discharge.
本研究基于厌氧发酵和微生物燃料电池(MFC),针对酶解预处理的剩余活性污泥(WAS),开发了一种从废水中同时回收电能和资源的综合方法。经过 3 小时的酶预处理(水解酶混合物导致超过 5300mg/L 的可溶性 COD 释放),WAS 得到了溶解,经过 10 天的发酵后,产生了 3580mg COD/L 的挥发性脂肪酸(VFA)。固液分离后,高 VFA 含量的发酵液被送入 MFC 以产生电能,而固体残渣则用于制造建筑材料(如混合水泥)。结果表明,发酵液(VFA)的电能转化率达到 1.254kW·h/kg COD,有机物去除率超过 90%,固体残渣可作为生产水泥的合格替代品进行消耗。因此,本研究可能为未来的剩余活性污泥管理提供一些新思路,以实现电能和资源回收,同时零排放二次废物。