关于“离子液体对低浓度CO的高效可逆捕获的预组织与合作”的通信
Correspondence on "Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO by Ionic Liquids".
作者信息
Zanatta Marcileia, Simon Nathalia M, Dos Santos Francisco P, Corvo Marta C, Cabrita Eurico J, Dupont Jairton
机构信息
Institute of Chemistry-, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves, 9500, Porto Alegre, 91501-970, RS, Brazil.
I3NCENIMAT, Dep. Ciência dos Materiais, Fac. Ciências e Tecnologia, UNL, 2829-516, Caparica, Portugal.
出版信息
Angew Chem Int Ed Engl. 2019 Jan 8;58(2):382-385. doi: 10.1002/anie.201712252. Epub 2018 Dec 11.
The preorganization and cooperation mechanism of imide-based ionic liquids reported in a recent Communication was evocated to rationalize the extremely high gravimetric CO capture displayed by these fluids. An analysis of the reported spectroscopic evidences together with additional experiments led to the proposition of an alternative, simpler, and feasible mechanism involving the formation of bicarbonate.
最近一篇通讯报道中提到的基于酰亚胺的离子液体的预组织和合作机制被唤起，以解释这些流体所显示出的极高的重量法二氧化碳捕获量。对所报道的光谱证据以及额外实验的分析导致提出了一种涉及碳酸氢盐形成的替代、更简单且可行的机制。
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