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对聚苯胺吸附气态氨和甲苯行为的对比研究。

Comparable investigation of polyaniline behavior towards gaseous ammonia and toluene adsorption.

机构信息

Chemical and Petrochemicals Engineering Department, Egypt-Japan University of Science and Technology, New Borg El-Arab Alexandria, Egypt.

Occupational Health and Air Pollution Department, High Institute of Public Health, Alexandria University, Alexandria, Egypt.

出版信息

Environ Sci Pollut Res Int. 2019 Feb;26(4):3991-3999. doi: 10.1007/s11356-018-3877-y. Epub 2018 Dec 14.

Abstract

With raising awareness of gaseous air pollutants and their harmful impact, adsorption is considered one of the most prominent techniques for gaseous emissions control. The usage of polyaniline as a gas adsorbent is an innovative idea. This work aims to compare the efficacy of synthesized polyaniline nanotubes (PANT) as a novel adsorbent towards inorganic gases (ammonia NH) and volatile organic compounds (toluene vapor). PANT was prepared via a sol-gel preparation technique. The molecular structure of prepared PANT was characterized by Fourier-transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The morphological structure was confirmed using transmission electron microscopy (TEM) and scanning electron microscope (SEM). The PANT adsorbent surface area was determined using Brunner Emmett Teller (BET). Dynamic behavior of simulated feed gas mixture of NH and toluene in air were examined using a fixed bed adsorption arrangement. The same adsorption conditions (inlet concentration, gas mixture feed flow rate, and a fixed amount of adsorbent) were applied for both NH and toluene adsorption test. The NH and toluene removal efficiencies were 100% and 96% respectively. Consequently, PANT is an auspicious adsorbent that can be utilized to control the indoor and outdoor gaseous air emissions. Graphical Abstracts ᅟ.

摘要

随着人们对气态空气污染物及其有害影响认识的提高,吸附被认为是控制气态排放的最突出技术之一。将聚苯胺用作气体吸附剂是一个创新的想法。本工作旨在比较合成的聚苯胺纳米管(PANT)作为一种新型吸附剂对无机气体(氨 NH)和挥发性有机化合物(甲苯蒸气)的效果。PANT 通过溶胶-凝胶制备技术制备。通过傅里叶变换红外光谱(FTIR)和 X 射线衍射(XRD)对制备的 PANT 的分子结构进行了表征。使用透射电子显微镜(TEM)和扫描电子显微镜(SEM)确认了形态结构。通过 Brunner Emmett Teller(BET)确定了 PANT 吸附剂的表面积。使用固定床吸附装置研究了模拟空气中 NH 和甲苯混合气的动态行为。NH 和甲苯吸附测试采用相同的吸附条件(入口浓度、混合气进料流速和固定量的吸附剂)。NH 和甲苯的去除效率分别为 100%和 96%。因此,PANT 是一种有前途的吸附剂,可用于控制室内和室外气态空气排放。

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