Studies on the molecular dynamics of acetylated oligosaccharides of different topologies (linear versus cyclic).

In this paper, the molecular dynamics and thermal properties of representative acetylated linear and cyclic oligosaccharides: acTRE, acRAF, acSTA, ac-α-CD, ac-β-CD, ac-γ-CD, have been investigated by using broadband dielectric spectroscopy and differential scanning calorimetry. We found that there are marked differences in the dynamics of the structural and secondary relaxation processes in both groups of materials. Just to mention a variation in the distribution of the structural relaxation times as well as different evolutions of the glass transition temperature (T) and fragility (m) versus molecular weight (M), which seem to be affected by the shape of the molecule, strain in the carbohydrate ring and mobility of side acetyl moieties.