Department of Physics, Chalmers University of Technology, SE-412 96 Gothenburg, Sweden.
Chem Commun (Camb). 2019 Jan 16;55(5):632-635. doi: 10.1039/c8cc07076h. Epub 2018 Dec 17.
Mixing the standard battery salt LiTFSI with various Li-salts of novel pseudo-delocalized organic anions [N(CH)((CH)SO)((CH)SO)] (MM), results in super-cooled solvent-free liquid electrolytes with glass transition temperatures of ca. 50 °C. Synthesis routes and full chemical characterisation of the new pseudo-delocalized anions are presented, as well as phase and thermal stabilities. The ion conductivities and electrochemical stabilities are evaluated towards lithium and sodium battery application.
将标准电池盐 LiTFSI 与各种新型拟离域有机阴离子 [N(CH)((CH)SO)((CH)SO)] (MM) 的 Li 盐混合，可得到具有约 50°C 玻璃化转变温度的无溶剂超冷液体电解质。本文介绍了新的拟离域阴离子的合成路线和全化学特性，以及它们的相和热稳定性。评估了它们对锂和钠电池应用的离子电导率和电化学稳定性。
