一种具有两个不同极性结合位点的单核 Pd(ii)-笼。
A mono-metallic Pd(ii)-cage featuring two different polar binding sites.
机构信息
Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST), Av. Països Catalans, 16, 43007, Tarragona, Spain.
出版信息
Chem Commun (Camb). 2019 Jan 10;55(5):604-607. doi: 10.1039/c8cc09195a.
PMID:30565593
Abstract
The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(ii)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed.
摘要
四-α异构体的超芳基扩展四吡啶杯[4]吡咯自组装成具有两个不同且会聚的极性结合位点的单金属 Pd(ii)-笼。单和双极性客体可逆地结合在笼中。提出了笼配合物中客体交换的机制。
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