Song Huimin, Wang Naizheng, Jiang Xingxing, Fu Ying, Li Yunfei, Liu Wang, Lin Zheshuai, Yao Jiyong, Zhang Guochun
Center for Crystal Research and Development, Key Laboratory of Functional Crystals and Laser Technology of Chinese Academy of Sciences , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences , Beijing 100190 , P.R. China.
Center of Materials Science and Optoelectronics Engineering , University of Chinese Academy of Sciences , Beijing 100049 , P.R. China.
Inorg Chem. 2019 Jan 22;58(2):1016-1019. doi: 10.1021/acs.inorgchem.8b03282. Epub 2018 Dec 31.
Two aluminoborates (LiZnSrAlBO and LiMgSrAlBO) and one galloborate (LiZnSrGaBO) were successfully obtained for the first time, and the centimeter-sized crystals were grown by the Kyropoulos method. These crystals possess the [MBO] (M = Al, Ga) basic frameworks in their crystal structures, and the [GaBO] framework is a new framework in galloborates. The synthesis, single crystal growth, characterizations, and theoretical calculation are reported for these compounds.
首次成功获得了两种铝硼酸盐（LiZnSrAlBO和LiMgSrAlBO）和一种镓硼酸盐（LiZnSrGaBO），并通过基罗普洛斯法生长出了厘米级的晶体。这些晶体在其晶体结构中具有[MBO]（M = Al，Ga）基本骨架，且[GaBO]骨架是镓硼酸盐中的一种新骨架。报道了这些化合物的合成、单晶生长、表征及理论计算。
