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捷克共和国利布契采一座废弃金矿区域内风险元素的土壤-植物转移

The soil-plant transfer of risk elements within the area of an abandoned gold mine in Libčice, Czech Republic.

作者信息

Umlaufová Martina, Száková Jiřina, Najmanová Jana, Sysalová Jiřina, Tlustoš Pavel

机构信息

a Department of Agroenvironmental Chemistry and Plant Nutrition , Czech University of Life Sciences Prague , Prague , Czech Republic.

b AAS laboratory , University of Chemistry and Technology , Prague , Czech Republic.

出版信息

J Environ Sci Health A Tox Hazard Subst Environ Eng. 2018;53(14):1267-1276. doi: 10.1080/10934529.2018.1528041. Epub 2018 Dec 30.

Abstract

Abandoned gold mines are often suggested as potential sources of environmental pollution. Thus, the soils within the area of a gold mine in Libčice, Czech Republic, were monitored. Elevated element contents were found of As, Cd, Cu, Hg, Pb, and Zn. The risk assessment codes (RACs) indicated high environmental risk from soil Cd, and moderate risk from Zn, whereas the risk of As, Cu, and Pb was low. It was supported by the analysis of 134 samples of aboveground biomass of plants, where the levels of As and Pb were below the detection limit. For Cd, the plant uptake reflected the high mobility of this element, where the bioaccumulation factors (BAFs) varied in range 0.032 (Fragaria vesca) and 1.97 (Circia arvensis). For 11% of samples the BAF values for Cd exceeded 1. For Hg, although the maximum BAF did not exceed 0.37 (Lotus corniculatus), the Hg contents in plants occasionally exceeded the threshold limits for Hg contents in raw feedstuffs. The investigated gold mine does not represent a direct environmental risk, but the fate of Cd and Hg in the soils and plants suggests the necessity of a deeper understanding of the penetration of these elements into the surrounding environment.

摘要

废弃金矿常被认为是潜在的环境污染源。因此,对捷克共和国利布契采一座金矿区域内的土壤进行了监测。发现砷、镉、铜、汞、铅和锌的元素含量有所升高。风险评估代码(RACs)表明土壤镉存在高环境风险,锌存在中度风险,而砷、铜和铅的风险较低。对134份植物地上生物量样本的分析支持了这一点,其中砷和铅的含量低于检测限。对于镉,植物吸收反映了该元素的高迁移性,生物累积因子(BAFs)在0.032(野草莓)至1.97(田蓟)范围内变化。11%的样本中镉的BAF值超过1。对于汞,尽管最大BAF不超过0.37(百脉根),但植物中的汞含量偶尔会超过原料中汞含量的阈值限制。所调查的金矿并不构成直接的环境风险,但土壤和植物中镉和汞的情况表明有必要更深入地了解这些元素向周围环境的渗透情况。

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