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监测埃及东南部土壤和一些野生植物中受污染有毒重金属,从尾矿到年龄积累的过程。

Monitoring of contaminated toxic and heavy metals, from mine tailings through age accumulation, in soil and some wild plants at Southeast Egypt.

机构信息

Chemistry Department, Aswan Faculty of Science, South Valley University, 81528 Aswan, Egypt.

出版信息

J Hazard Mater. 2010 Jun 15;178(1-3):739-46. doi: 10.1016/j.jhazmat.2010.01.147. Epub 2010 Feb 4.

Abstract

This study includes tailing from gold mine, at Allaqi Wadi Aswan, Egypt, used by incident Egyptian and after by some English companies. Tailings, soils and wild plants (Acia Raddiena and Aerva Javanica) were sampled and analysed for toxic metals (Hg, Cd, Pb and As) and associated heavy metals (Cr, Ag, Ni, Au, Mo, Zn, Mn and Cu) using ICP-MS, ICP-AES, CVAAS and FAAS techniques. The present work concerns the distribution and mobility of these metals from tailing to the surrounding soils and wild flora. The results reveal that Cr, Cu, Zn, Ni, Ag, Au, Mn, Hg, As, Ag, Au and Pb in soil decreased as faraway from the tailing, after then irregular trends as a result of input from surrounding rocks. Acia Raddiena plant accumulated As, Cd and Pb in higher levels than Aerva Javanica. Quantification of soil and plant pollution was studied using enrichment factors, contamination factor, pollution index and bioaccumulation factors and show good interpretations of the results. The overall results of this study show that the soil and plants near the gold mine tailing were highly toxic, and the plants and soil must not be uses for grazing or agriculture.

摘要

本研究包括来自埃及阿斯旺阿拉基瓦迪金矿的尾矿,曾被埃及当地和后来的一些英国公司使用。尾矿、土壤和野生植物(相思树和 Aerva Javanica)被取样并分析了有毒金属(汞、镉、铅和砷)以及相关重金属(铬、银、镍、金、钼、锌、锰和铜),采用 ICP-MS、ICP-AES、CVAAS 和 FAAS 技术。本工作关注这些金属从尾矿到周围土壤和野生植物中的分布和迁移。结果表明,随着远离尾矿,土壤中的 Cr、Cu、Zn、Ni、Ag、Au、Mn、Hg、As、Ag、Au 和 Pb 减少,然后由于周围岩石的输入,呈现出不规则的趋势。相思树植物比 Aerva Javanica 更大量地积累砷、镉和铅。使用富集因子、污染因子、污染指数和生物累积因子研究了土壤和植物污染的量化,并对结果进行了很好的解释。本研究的总体结果表明,金矿尾矿附近的土壤和植物具有高度毒性,这些植物和土壤不能用于放牧或农业。

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