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Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones.
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α-Amination of keto-nitrones via multihetero-Cope rearrangement employing an imidoyl chloride reagent.
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Direct catalytic asymmetric mannich reactions of malonates and beta-keto esters.
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α-Imino Esters in Organic Synthesis: Recent Advances.
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Umpolung Reactions of α-Imino Esters: Useful Methods for the Preparation of α-Amino Acid Frameworks.
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Synthesis of tertiary alpha-hydroxy acids by silylene transfer to alpha-keto esters.
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Catalytic Enantioselective [3 + 2] Cycloaddition of α-Keto Ester Enolates and Nitrile Oxides.
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Development of New Reactions Driven by N-O Bond Cleavage: from -Acyl Hydroxylamines to Tetrodotoxin.
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OBO-Protected Pyruvates as Reagents for the Synthesis of Functionalized Heteroaromatic Compounds.
Org Lett. 2018 Jul 6;20(13):4048-4051. doi: 10.1021/acs.orglett.8b01614. Epub 2018 Jun 15.
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Palladium-Catalyzed β-Arylation of α-Keto Esters.
Org Lett. 2017 Apr 21;19(8):2126-2129. doi: 10.1021/acs.orglett.7b00761. Epub 2017 Apr 11.
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Rearrangement of N-oxyenamines and related reactions.
Chem Rev. 2014 May 28;114(10):5426-76. doi: 10.1021/cr400196x. Epub 2014 Mar 14.
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α-Amination of keto-nitrones via multihetero-Cope rearrangement employing an imidoyl chloride reagent.
Chem Commun (Camb). 2012 Aug 7;48(61):7568-70. doi: 10.1039/c2cc33401a. Epub 2012 Jun 26.
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A general method for the alpha-acyloxylation of carbonyl compounds.
Org Lett. 2005 Dec 8;7(25):5729-32. doi: 10.1021/ol052474e.
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Bacterial L-serine dehydratases: a new family of enzymes containing iron-sulfur clusters.
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