School of Environmental Science and Engineering, State Key Lab of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China.
Chem Commun (Camb). 2019 Jan 22;55(8):1056-1059. doi: 10.1039/c8cc08075e.
H2S is considered to be an important reductant in abiotic CO2 reduction to organics, however, almost no experimental support has been reported. Herein, the first observation of CO2 reduction to formate with H2S under alkaline hydrothermal conditions is reported, and water is found to act as a hydrogen donor.
H2S 被认为是生物非还原 CO2 转化为有机化合物的重要还原剂，但几乎没有实验证据支持。本文首次报道了在碱性水热条件下 H2S 将 CO2 还原为甲酸盐的反应，并且发现水是氢供体。
