Suppr超能文献

[ZnTiO/TiO光催化剂的制备及其对有机污染物光催化降解的机理]

[Preparation of ZnTiO/TiO Photocatalyst and Its Mechanism on Photocatalytic Degradation of Organic Pollutants].

作者信息

Zhang Wen-Hai, Ji Qing-Hua, Lan Hua-Chun, Li Jing

机构信息

School of Civil and Transportation Engineering, Hebei University of Technology, Tianjin 300401, China.

Center for Water and Ecology, Tsinghua University, Beijing 100084, China.

出版信息

Huan Jing Ke Xue. 2019 Feb 8;40(2):693-700. doi: 10.13227/j.hjkx.201807017.

Abstract

TiO is a promising photocatalysis for degradation of organic pollutants due to its innocuity. However, its widespread practical application was hindered by the fast combination speed of photogenerated electron-hole pairs and low quantum efficiency. In this study, we prepared ZnTiO-TiO using the Sol-Gel method to get heterojunctions, which exhibit efficient separation of photogenerated electron-hole pairs. The photocatalytic performances of various ZnTiO-TiO were evaluated by the removal efficiency of Methyl orange. The experimental results showed that the ZnTiO-TiO(ZnTiO:TiO=0.3), which was calcinated under 600℃, had the best photocatalytic activity under ultraviolet light. The photocatalyst was stable under a wide range of pH (2.5-12.5). The photocurrent and ESR analysis verified the superior photocatalysis of ZnTiO-TiO, which was attributed to the efficient separation of electron-hole pairs induced by the heterojunctions.

摘要

由于TiO无毒,它是一种很有前途的用于降解有机污染物的光催化剂。然而,光生电子-空穴对的快速复合速度和低量子效率阻碍了它的广泛实际应用。在本研究中,我们采用溶胶-凝胶法制备了ZnTiO-TiO以形成异质结,该异质结表现出光生电子-空穴对的有效分离。通过甲基橙的去除效率评估了各种ZnTiO-TiO的光催化性能。实验结果表明,在600℃下煅烧的ZnTiO-TiO(ZnTiO:TiO = 0.3)在紫外光下具有最佳的光催化活性。该光催化剂在较宽的pH范围(2.5 - 12.5)内稳定。光电流和电子自旋共振分析证实了ZnTiO-TiO的优异光催化性能,这归因于异质结诱导的电子-空穴对的有效分离。

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验