Zhang Wen-Hai, Ji Qing-Hua, Lan Hua-Chun, Li Jing
School of Civil and Transportation Engineering, Hebei University of Technology, Tianjin 300401, China.
Center for Water and Ecology, Tsinghua University, Beijing 100084, China.
Huan Jing Ke Xue. 2019 Feb 8;40(2):693-700. doi: 10.13227/j.hjkx.201807017.
TiO is a promising photocatalysis for degradation of organic pollutants due to its innocuity. However, its widespread practical application was hindered by the fast combination speed of photogenerated electron-hole pairs and low quantum efficiency. In this study, we prepared ZnTiO-TiO using the Sol-Gel method to get heterojunctions, which exhibit efficient separation of photogenerated electron-hole pairs. The photocatalytic performances of various ZnTiO-TiO were evaluated by the removal efficiency of Methyl orange. The experimental results showed that the ZnTiO-TiO(ZnTiO:TiO=0.3), which was calcinated under 600℃, had the best photocatalytic activity under ultraviolet light. The photocatalyst was stable under a wide range of pH (2.5-12.5). The photocurrent and ESR analysis verified the superior photocatalysis of ZnTiO-TiO, which was attributed to the efficient separation of electron-hole pairs induced by the heterojunctions.
由于TiO无毒,它是一种很有前途的用于降解有机污染物的光催化剂。然而,光生电子-空穴对的快速复合速度和低量子效率阻碍了它的广泛实际应用。在本研究中,我们采用溶胶-凝胶法制备了ZnTiO-TiO以形成异质结,该异质结表现出光生电子-空穴对的有效分离。通过甲基橙的去除效率评估了各种ZnTiO-TiO的光催化性能。实验结果表明,在600℃下煅烧的ZnTiO-TiO(ZnTiO:TiO = 0.3)在紫外光下具有最佳的光催化活性。该光催化剂在较宽的pH范围(2.5 - 12.5)内稳定。光电流和电子自旋共振分析证实了ZnTiO-TiO的优异光催化性能,这归因于异质结诱导的电子-空穴对的有效分离。