You Wen, Liu Hai-Cheng, Cao Jia-Wei, Shen Yao-Liang, Chen Wei
School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China.
Ministry of Education, Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Hohai University, Nanjing 210098, China.
Huan Jing Ke Xue. 2018 Dec 8;39(12):5532-5540. doi: 10.13227/j.hjkx.201803074.
For high-efficiency removal of humic acid (HA), a natural organic matter in the water source, an adsorbent named magnetically modified chitosan-grafted polyacrylamide (MC-g-PAM) was developed by using an coprecipitation method. Analytical instruments, such as a Fourier transform infrared (FTIR) spectroscope, scanning electron microscope (SEM), vibrating sample magnetometer (VSM), and specific surface area tester (BET), were used to characterize and analyze this material. With the aid of batch tests, the removal efficiency and mechanism of humic acid in water samples were investigated. The results show that the specific surface area and specific saturation magnetization values of the prepared MC-g-PAM are 27.065 m·g and 9.63 emu·g, respectively. The adsorption of humic acid by MC-g-PAM is an endothermic process and the Langmuir isotherm model and the pseudo-second-order kinetic equation fit the adsorption process well. At 25℃, the equilibrium adsorption capacity of MC-g-PAM to humic acid reaches 120.77 mg·g.
为了高效去除水源中的天然有机物腐殖酸(HA),采用共沉淀法制备了一种名为磁性改性壳聚糖接枝聚丙烯酰胺(MC-g-PAM)的吸附剂。利用傅里叶变换红外(FTIR)光谱仪、扫描电子显微镜(SEM)、振动样品磁强计(VSM)和比表面积测试仪(BET)等分析仪器对该材料进行表征和分析。借助批量试验,研究了水样中腐殖酸的去除效率和机理。结果表明,制备的MC-g-PAM的比表面积和比饱和磁化强度值分别为27.065 m²·g 和9.63 emu·g。MC-g-PAM对腐殖酸的吸附是一个吸热过程,Langmuir等温线模型和准二级动力学方程能很好地拟合吸附过程。在25℃时,MC-g-PAM对腐殖酸的平衡吸附量达到120.77 mg·g 。