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基于卟啉的铀有机框架的(3,4)连接的pto 和 tbo 拓扑结构的组装。

Assembly of porphyrin-based uranium organic frameworks with (3,4)-connected pto and tbo topologies.

机构信息

Institute of Materials, China Academy of Engineering Physics, Mianyang 621907, China.

State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China.

出版信息

Dalton Trans. 2019 Feb 7;48(5):1595-1598. doi: 10.1039/c8dt04585b. Epub 2019 Jan 10.

DOI:10.1039/c8dt04585b
PMID:30629050
Abstract

Three (3,4)-connected uranyl-organic frameworks (UOFs) with pto and tbo topologies were synthesized. The UOF with a pto net possesses a 2-fold interpenetrating network and exhibits 2D interconnected channels. The UOF with a tbo net is constructed from two types of ultralarge nanocages. All these compounds can efficiently remove large cationic dye crystal violet (CV) through a cation exchange mechanism.

摘要

三种(3,4)-连接的铀-有机骨架(UOFs)具有 pto 和 tbo 拓扑结构被合成。具有 pto 网络的 UOF 具有 2 重穿插网络,并表现出 2D 相互连接的通道。具有 tbo 网络的 UOF 由两种类型的超大纳米笼构成。所有这些化合物都可以通过阳离子交换机制有效地去除大阳离子染料结晶紫(CV)。

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