具有内部庞大配位配体的扭曲大环六核钯配合物。

A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands.

机构信息

Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan.

出版信息

Chem Commun (Camb). 2019 Feb 21;55(17):2421-2424. doi: 10.1039/c8cc09643k.

DOI:10.1039/c8cc09643k

PMID:30633271

Abstract

A macrocyclic hexanuclear palladium complex, which accumulates coordination sites on metals inside the cavity, was synthesized. The macrocycle was found to take a uniquely-twisted C2-symmetric conformation when six molecules of a bulky pyridine derivative coordinated to the palladium.

摘要

合成了一种大环六核钯配合物，该配合物在空腔内的金属上积累了配位位点。当六个大位吡啶衍生物分子与钯配位时，大环被发现具有独特的扭曲 C2 对称构象。