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在可见光/近红外光照射下,由磷酸铜(Ⅱ)氢氧化物包覆的光催化自清洁棉织物。

Photocatalytic Self-Cleaning Cotton Fabrics Coated by Cu₂(OH)PO₄ under VIS/NIR Irradiation.

作者信息

Gao Dawei, Wang Lili, Wang Chunxia, Chen Tan

机构信息

Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, China.

College of Textiles and Clothes, Yancheng Institute of Technology, Yancheng 224051, China.

出版信息

Materials (Basel). 2019 Jan 11;12(2):238. doi: 10.3390/ma12020238.

Abstract

In the present work, a mild strategy was employed to obtain cotton fabrics (CFs) coated with Cu₂(OH)PO₄ (CHP) nanoparticles to achieve self-cleaning property. The phytic acid (IP6) assisted method was employed to synthesize nanoparticles (CHP-IP6). The as-prepared coated cotton fabrics were characterized using the following techniques: Fourier-transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The CHP-IP6 coated cotton fabrics showed significant photocatalytic activity, excellent photocatalytic stability, and good discoloration of methylene blue (MB) stains when exposed to sunlight, which could have important applications as tablecloths, household apparels, and industrial workwear.

摘要

在本工作中,采用了一种温和的策略来制备涂覆有磷酸铜(Ⅱ)氢氧化物(CHP)纳米颗粒的棉织物(CFs),以实现自清洁性能。采用植酸(IP6)辅助法合成纳米颗粒(CHP-IP6)。使用以下技术对所制备的涂覆棉织物进行表征:傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、扫描电子显微镜(SEM)、能量色散X射线(EDX)分析、透射电子显微镜(TEM)、X射线光电子能谱(XPS)和热重分析(TGA)。CHP-IP6涂覆的棉织物在暴露于阳光时表现出显著的光催化活性、优异的光催化稳定性以及对亚甲基蓝(MB)污渍的良好褪色效果,这在用作桌布、家用服装和工业工作服方面可能具有重要应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fbe0/6356686/ac6b88659941/materials-12-00238-g001.jpg

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