溶剂导向控制在正方形格子（sql）配位网络中的缠结拓扑。
Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks.
机构信息
Department of Chemical Sciences and Bernal Institute, University of Limerick, Castletroy Co, Limerick, Y94T9PX, Ireland.
出版信息
Chem Commun (Camb). 2019 Jan 29;55(10):1454-1457. doi: 10.1039/c8cc09152h.
PMID:30644471
Abstract
We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel-inclined 2D → 3D polycatenation).
摘要
我们在此报告，通过使用不同溶剂在溶剂热合成过程中，可以控制由扩展双咪唑配体 L 形成的方格子 sql 配位网络的纠缠模式。[ML2(NO3)2]n（M = Co，Ni）表现出平行的 2D→2D 贯穿，并且异常地表现出混合纠缠（平行倾斜 2D→3D 多锁链）。
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