显著增强的 PuO2 在功能化离子液体中的直接溶解：电化学和理论研究的见解。

Remarkably enhanced direct dissolution of plutonium oxide in task-specific ionic liquid: insights from electrochemical and theoretical investigations.

机构信息

Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085, India.

出版信息

Chem Commun (Camb). 2019 Jan 29;55(10):1474-1477. doi: 10.1039/c8cc10256b.

Abstract

The present work envisages an approach for direct dissolution of PuO2 in a task-specific ionic liquid (TSIL). An attractive possibility to electrodeposit plutonium from the mixture of TSIL and PuO2 has been explored further. The carboxyl functional group attached to the TSIL plays a key role in facilitating the dissolution of plutonium ions.

摘要

本工作设想了一种直接将 PuO2 溶解在特定功能离子液体（TSIL）中的方法。进一步探索了从 TSIL 和 PuO2 的混合物中电化学沉积钚的有吸引力的可能性。连接到 TSIL 的羧基官能团在促进钚离子溶解方面起着关键作用。