Two-dimensional hexagonal boron nitride nanosheet as the planar-alignment agent in a liquid crystal-based electro-optic device.

The planar-alignment agent in an electro-optic liquid crystal (LC) device plays an essential role for the LC's electro-optical characteristics. Rubbed polyimide (PI) layers are conventionally used as the planar-alignment agent in traditional liquid crystal displays (LCDs). Here we experimentally demonstrate that the 2D hexagonal boron nitride (h-BN) nanosheet can serve as the planar-alignment agent in an LC cell. This h-BN has higher chemical stability and more optical transparency than the PI layer. Two h-BN-covered indium tin oxide (ITO) glass slides (without any conventional PI layers) are placed together to fabricate an LC cell. A nematic LC inside this h-BN-based cell exhibits uniform planar-alignment-which is probed by a crossed polarized optical microscope. This planar-alignment at the molecular scale is achieved due to the coherent overlay of the benzene rings of the LC molecules on the hexagonal BN lattice. This h-BN-based LC cell shows the typical electro-optical effect when an electric field is applied via ITO electrodes. The dielectric measurement across this h-BN-based electro-optic cell shows a standard Fréedericksz transition of the LC, confirming that the 2D h-BN, as the planar-alignment agent, supplies adequate anchoring energy-which can be overcome by the Fréedericksz threshold voltage. Finally, we show that the h-BN-based LC cell exhibits more optical transparency than a regular PI alignment layer-based LC cell.