Li Junli, Liu Jikang, Liu Xiangfu, Wang Rongwen, Zhang Jian, Tu Guoli
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road, Hongshan district, Wuhan, Hubei, 430074, P. R. China.
School of Material Science and Technology, Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, 1st Jinji Road, Guilin, Guangxi, 541004, P. R. China.
ChemSusChem. 2019 Apr 5;12(7):1401-1409. doi: 10.1002/cssc.201802939. Epub 2019 Feb 27.
An eco-friendly n-type water/alcohol-soluble conjugated polyelectrolyte PF SO Li was synthesized and applied as a cathode interfacial layer in organic solar cells. The π-delocalized polyfluorene backbone has an intimate connection with the hydrophobic active layer, and the side chain with lithium ion may move toward the ZnO layer through the self-assembly property of conjugated polyelectrolytes. UV photoelectron spectroscopy indicated that modification with PF SO Li dramatically lowers the work function of indium-doped tin oxide (ITO)/ZnO and may form strong interfacial dipoles between ZnO and the active layer. Meanwhile, introduction of lithium ions as spectator cations may contribute to reduction of the intrinsic surface defects of ZnO. The green emission in the photoluminescence spectrum of ZnO disappeared after modification with PF SO Li. In addition, the roughness of ZnO barely changed after coating with PF SO Li, and the surface became more hydrophobic, which demonstrates that the thin conjugated polyelectrolyte layer exhibits good adhesion with both ZnO and the active layer. These phenomena indicate that the introduction of PF SO Li makes ITO/ZnO an efficient cathode. As a result, inverted organic solar cell devices with ZnO/PF SO Li double-interlayers exhibit high efficiencies of 11.7 and 10.6 % for PBDB-T:IT-M and PBDB-T:ITIC blend systems, respectively.
