用于环状碳酸酯合成的多功能可持续铁-亚氨基吡啶配合物
Multifunctional and Sustainable Fe-Iminopyridine Complexes for the Synthesis of Cyclic Carbonates.
作者信息
Seong Eun Young, Kim Jae Hyung, Kim Nam Hee, Ahn Kwang-Hyun, Kang Eun Joo
机构信息
Department of Applied Chemistry, Kyung Hee University, Yongin, 17104, Korea.
出版信息
ChemSusChem. 2019 Jan 24;12(2):409-415. doi: 10.1002/cssc.201802563. Epub 2019 Jan 17.
PMID:30654413
Abstract
The use of multifunctional and sustainable Fe catalysts for the formation of cyclic carbonates from epoxides and carbon dioxide at 80 °C and 3 bar pressure is presented. The optimal catalyst possesses a halide counteranion and a hydrogen bond donor to activate the epoxide for ring opening, affording a single-component, cocatalyst-free catalytic system.
摘要
介绍了在80°C和3巴压力下使用多功能且可持续的铁催化剂由环氧化物和二氧化碳形成环状碳酸酯的方法。最佳催化剂具有卤化物抗衡阴离子和氢键供体，可活化环氧化物以进行开环反应，从而提供一种单组分、无助催化剂的催化体系。
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