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电纺丝技术制备载没食子酸羟丙基甲基纤维素纳米纤维作为活性包装材料。

Fabrication of gallic acid loaded Hydroxypropyl methylcellulose nanofibers by electrospinning technique as active packaging material.

机构信息

Department of Food Engineering, Middle East Technical University, 06800, Ankara, Turkey.

Department of Food Engineering, Middle East Technical University, 06800, Ankara, Turkey.

出版信息

Carbohydr Polym. 2019 Mar 15;208:241-250. doi: 10.1016/j.carbpol.2018.12.065. Epub 2018 Dec 21.

Abstract

The objective of this study was to encapsulate gallic acid in Hydroxypropyl methylcellulose (HPMC)/ polyethylene oxide (PEO) blend nanofiber by using electrospinning and examine the usage of nanofibers as active packaging materials. Gallic acid loaded nanofibers showed homogenous morphology. Gallic acid was loaded into nanofibers efficiently and nanofibers showed strong antioxidant activity. As the gallic acid amount increased, the TGA curves had shifted one stage to two stage degradation and degradation temperature (T) of gallic acid decreased from 275 °C to 250 °C due to the crystalline structure change. Interaction between gallic acid and HPMC/PEO nanofiber demonstrated that gallic acid successfully embedded into the nanofibers. Gallic acid loaded nanofibers decreased the oxidation of walnut during storage. Overall, electrospinning technique was proved to be an efficient method to encapsulate bioactive compounds and gallic acid loaded nanofibers showed promissory results that can be suggested as great potential to active packaging material.

摘要

本研究的目的是通过静电纺丝将没食子酸包埋在羟丙基甲基纤维素(HPMC)/聚氧化乙烯(PEO)共混纳米纤维中,并研究纳米纤维作为活性包装材料的用途。负载没食子酸的纳米纤维呈现均匀的形态。没食子酸有效地负载到纳米纤维中,并且纳米纤维表现出很强的抗氧化活性。随着没食子酸含量的增加,TGA 曲线从单阶段降解转变为两阶段降解,由于结晶结构的变化,没食子酸的降解温度(T)从 275°C 降低到 250°C。没食子酸与 HPMC/PEO 纳米纤维之间的相互作用表明,没食子酸成功地嵌入到纳米纤维中。负载没食子酸的纳米纤维降低了核桃在储存过程中的氧化。总的来说,静电纺丝技术被证明是一种有效的包埋生物活性化合物的方法,负载没食子酸的纳米纤维表现出有希望的结果,可以作为活性包装材料的巨大潜力。

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