Kolaczkowski Matthew A, Liu Yi
The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, CA 94720, United States.
College of Chemistry, University of California, Berkeley, Berkeley, CA 94720, United States.
Chem Rec. 2019 Jun;19(6):1062-1077. doi: 10.1002/tcr.201800159. Epub 2019 Jan 21.
The advancement of organic electronics has been continually pushed by the need for stable and high performance acceptor materials. By utilizing inexpensive and stable indigo dye as a starting material, Bay-Annulated Indigo (BAI) provides a new motif for the development of semiconducting materials. Modular and straightforward synthesis makes BAI an outstanding platform for molecular design, while excellent stability, strong absorption, and high ambipolar mobility render BAI-based materials excellent candidates for organic electronics. BAI-based polymers and small molecules have taken advantage of these properties to show promising results in a variety of applications.
对稳定且高性能受体材料的需求不断推动着有机电子学的发展。通过使用廉价且稳定的靛蓝染料作为起始材料,湾区稠合靛蓝(BAI)为半导体材料的开发提供了一种新的结构单元。模块化且简便的合成方法使BAI成为分子设计的出色平台,而优异的稳定性、强吸收性和高双极性迁移率使基于BAI的材料成为有机电子学的优秀候选材料。基于BAI的聚合物和小分子利用这些特性在各种应用中展现出了有前景的结果。