Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry , Sichuan University , 29 Wangjiang Road , Chengdu 610064 , P.R. China.
Org Lett. 2019 Feb 1;21(3):797-801. doi: 10.1021/acs.orglett.8b04059. Epub 2019 Jan 22.
A novel naphthotetraindole (NTI) core was synthesized in two steps via the McMurry reaction and a [Cu]/[Ag]-promoted intramolecular dehydrogenative homocoupling reaction. NTI shows a unique X-shaped double-helical structure as determined by single-crystal X-ray diffraction analysis. The hole-transport mobility of the bare NTI core was measured to be 2.3 × 10 cm V s, which is comparable with the commonly used Spiro-OMeTAD.
一种新型萘四并吲哚（NTI）核心通过麦克默里反应和[Cu]/[Ag]促进的分子内脱氢偶联反应两步合成。NTI 通过单晶 X 射线衍射分析确定具有独特的 X 形双螺旋结构。裸 NTI 核心的空穴传输迁移率被测量为 2.3×10^-5cm^2 V^-1 s^-1，与常用的 Spiro-OMeTAD 相当。
