Department of Chemistry , University of Idaho , Moscow , Idaho 83844-2343 , United States.
Naval Research Laboratory , 4555 Overlook Avenue , Washington , DC 20375 , United States.
Org Lett. 2019 Feb 15;21(4):1073-1077. doi: 10.1021/acs.orglett.8b04114. Epub 2019 Jan 23.
An oxygen-rich energetic compound, 1,3-bis(trinitromethyl)-1,2,4-triazole (13), was obtained by a two-step nitration and found to have an excellent crystal density of 1.90 g/cm confirmed by X-ray single-crystal diffraction. This highly dense material, as a green energetic oxidizer, features an attractive positive oxygen balance, an acceptable sensitivity, and a good enthalpy of formation, making it a competitive replacement for AP.
一种富氧高能化合物 1,3-双(三硝基甲基)-1,2,4-三唑（13）通过两步硝化得到，并通过 X 射线单晶衍射证实具有 1.90 g/cm3 的出色晶体密度。这种高密度材料作为一种绿色高能氧化剂，具有吸引人的正氧平衡、可接受的敏感度和良好的生成焓，是 AP 的有竞争力的替代品。
