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黑磷体相还原共价功能化过程中的晶格开孔

Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus.

作者信息

Wild Stefan, Fickert Michael, Mitrovic Aleksandra, Lloret Vicent, Neiss Christian, Vidal-Moya José Alejandro, Rivero-Crespo Miguel Ángel, Leyva-Pérez Antonio, Werbach Katharina, Peterlik Herwig, Grabau Mathias, Wittkämper Haiko, Papp Christian, Steinrück Hans-Peter, Pichler Thomas, Görling Andreas, Hauke Frank, Abellán Gonzalo, Hirsch Andreas

机构信息

Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Nikolaus-Fiebiger Strasse 10, 91058, Erlangen and Dr.-Mack Strasse 81, 90762 Fürth, Germany.

Lehrstuhl für Theoretische Chemie and Interdisciplinary Center of Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 3, 91058, Erlangen, Germany.

出版信息

Angew Chem Int Ed Engl. 2019 Apr 16;58(17):5763-5768. doi: 10.1002/anie.201811181. Epub 2019 Mar 21.

DOI:10.1002/anie.201811181
PMID:30675972
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7318246/
Abstract

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

摘要

利用黑磷插层化合物对薄层黑磷（BP）进行化学批量还原共价功能化已被开发出来。通过有效的还原活化，实现了带电BP与有机卤化物反应的共价功能化。通过几种光谱技术和密度泛函理论（DFT）计算广泛证明了功能化；产物显示出比通过中性途径获得的产物更高的功能化程度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/006e2e757bfa/ANIE-58-5763-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/4df1fad66ec4/ANIE-58-5763-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/348aceb758b1/ANIE-58-5763-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/1e3352678bc5/ANIE-58-5763-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/58edc8bab413/ANIE-58-5763-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/a22bb3b799eb/ANIE-58-5763-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/006e2e757bfa/ANIE-58-5763-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/4df1fad66ec4/ANIE-58-5763-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/348aceb758b1/ANIE-58-5763-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/1e3352678bc5/ANIE-58-5763-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/58edc8bab413/ANIE-58-5763-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/a22bb3b799eb/ANIE-58-5763-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ad1/7318246/006e2e757bfa/ANIE-58-5763-g004.jpg

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