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廉价且非氟化物的超疏水混凝土涂层,具有抗结冰和防腐蚀功能。

Inexpensive and non-fluorinated superhydrophobic concrete coating for anti-icing and anti-corrosion.

机构信息

Key Laboratory for Precision and Non-traditional Machining Technology of the Ministry of Education, Dalian University of Technology, Dalian 116024, China; Collaborative Innovation Center of Major Machine Manufacturing in Liaoning, Dalian University of Technology, Dalian 116024, China.

Key Laboratory for Precision and Non-traditional Machining Technology of the Ministry of Education, Dalian University of Technology, Dalian 116024, China.

出版信息

J Colloid Interface Sci. 2019 Apr 1;541:86-92. doi: 10.1016/j.jcis.2019.01.014. Epub 2019 Jan 6.

Abstract

Reinforced concrete is widely used in civil engineering due to its outstanding mechanical properties and low cost. However, icing and corrosion on concrete-based facilities such as roads, dams, and bridges often cause safety issues. Superhydrophobic surface with completely water-repellent properties that are inspired by the lotus leaf in nature, has great potential to solve this problem, however, most state-of-the-art and commercial superhydrophobic coatings are expensive and weak in mechanical robustness for large-scale application on concrete. Here, we developed an inexpensive, non-fluorinated, and robust superhydrophobic concrete (S-concrete) coating with a contact angle of 160 ± 1° and sliding angle of 6.5 ± 0.5°. This coating had a high surface mechanical strength and retained superhydrophobicity after blade scratch for several times or sandpaper abrasion for 20 m distance. The robust S-concrete coating also had a good anti-icing ability, a low deicing force, and a high corrosion resistance, which is expected to be applied on roads, buildings, bridges, and many other concrete-based facilities in large scale for anti-icing and anti-corrosion purposes.

摘要

由于其出色的机械性能和低成本,钢筋混凝土在土木工程中得到了广泛的应用。然而,道路、水坝和桥梁等基于混凝土的设施上的结冰和腐蚀问题经常会引发安全问题。受自然荷叶启发而具有完全疏水性能的超疏水表面具有解决这个问题的巨大潜力,然而,大多数最先进和商业上的超疏水涂层都很昂贵,而且在大规模应用于混凝土时机械强度较弱。在这里,我们开发了一种廉价、无氟且坚固的超疏水混凝土 (S-混凝土) 涂层,其接触角为 160±1°,滑动角为 6.5±0.5°。这种涂层具有较高的表面机械强度,经过多次刀片划伤或砂纸磨损 20 米距离后仍能保持超疏水性。坚固的 S-混凝土涂层还具有良好的抗结冰能力、较低的除冰力和较高的耐腐蚀性,有望大规模应用于道路、建筑物、桥梁和许多其他基于混凝土的设施,以达到抗结冰和耐腐蚀的目的。

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