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有序介孔材料在电池中的研究现状。

The State of Research Regarding Ordered Mesoporous Materials in Batteries.

机构信息

School of Chemistry and Chemical Engineering, Guangling College, Yangzhou University, Yangzhou, 225009, Jiangsu, P. R. China.

出版信息

Small. 2019 Mar;15(11):e1804600. doi: 10.1002/smll.201804600. Epub 2019 Jan 28.

Abstract

Ordered mesoporous materials, porous materials with a pore size of 2-50 nm which are prepared via the sol-gel process using surfactant molecular aggregates as a template to assemble channels through the interfacial action of organic and inorganic substances, have recently triggered a heated debate. In addition to applications in the catalytic cracking of heavy oils and residues, the manufacturing of graft materials, the purification of water, the conversion of automobile exhaust, biochips, and the treatment of environmental pollutants via photocatalysts, ordered mesoporous materials have drawn substantial attention in the field of electrochemical energy storage due to advantages such as large specific surface area, uniform and continuously adjustable pore size, and orderly arrangement. Here, a general summary and appraisal of the study of ordered mesoporous materials for batteries in recent years is given, including the synthesis methods, meso/nanostructural features, and electrochemical capabilities of such materials.

摘要

有序介孔材料是一种孔径为 2-50nm 的多孔材料,通过溶胶-凝胶过程制备,使用表面活性剂分子聚集体作为模板,通过有机和无机物质的界面作用组装通道。近年来,这种材料引发了激烈的争论。除了在重油和渣油的催化裂化、接枝材料的制造、水的净化、汽车尾气的转化、生物芯片以及光催化剂处理环境污染物等方面的应用外,有序介孔材料由于具有大的比表面积、均匀且可连续调节的孔径以及有序排列等优点,在电化学储能领域也引起了广泛关注。本文对近年来电池用有序介孔材料的研究进行了综述,包括其合成方法、介观/纳米结构特征和电化学性能。

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