Seppänen Heli, Kim Iurii, Etula Jarkko, Ubyivovk Evgeniy, Bouravleuv Alexei, Lipsanen Harri
Department of Electronics and Nanoengineering, Aalto University School of Electrical Engineering, P.O. Box 13500, FI-00076 Aalto, Finland.
St. Petersburg Academic State University, Ul. Khlopina 8/3, 194021 Saint Petersburg, Russia.
Materials (Basel). 2019 Jan 28;12(3):406. doi: 10.3390/ma12030406.
Aluminum nitride (AlN) films have been grown using novel technological approaches based on plasma-enhanced atomic layer deposition (PEALD) and in situ atomic layer annealing (ALA). The growth of AlN layers was carried out on Si<100> and Si<111> substrates at low growth temperature. The investigation of crystalline quality of samples demonstrated that PEALD grown layers were polycrystalline, but ALA treatment improved their crystallinity. A thick polycrystalline AlN layer was successfully regrown by metal-organic chemical vapor deposition (MOCVD) on an AlN PEALD template. It opens up the new possibilities for the formation of nucleation layers with improved quality for subsequent growth of semiconductor nitride compounds.
氮化铝(AlN)薄膜已通过基于等离子体增强原子层沉积(PEALD)和原位原子层退火(ALA)的新型技术方法生长而成。AlN层的生长是在Si<100>和Si<111>衬底上于低生长温度下进行的。对样品晶体质量的研究表明,PEALD生长的层是多晶的,但ALA处理改善了它们的结晶度。通过金属有机化学气相沉积(MOCVD)在AlN PEALD模板上成功地重新生长出了一层厚的多晶AlN层。这为形成具有更高质量的成核层开辟了新的可能性,以便后续生长半导体氮化物化合物。