N-混淆卟啉-氮杂二吡咯嵌合体：一种利用其独特的NH互变异构现象的多功能金属配位配体。
N-Confused Porphyrin-aza-Dipyrrin Chimera: A Versatile Metal Coordination Ligand Using its Unique NH Tautomerism.
作者信息
Fukuda Masaya, Mori Shigeki, Furuta Hiroyuki, Shimizu Soji
机构信息
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka, 819-0395, Japan.
Advanced Research Support Center (ADRES), Ehime University, Matsuyama, 790-8577, Japan.
出版信息
Chem Asian J. 2019 May 15;14(10):1697-1702. doi: 10.1002/asia.201801750. Epub 2019 Feb 1.
A novel N-confused porphyrin (NCP) analogue bearing an external aza-dipyrrin-like coordination site was synthesized by a Schiff-base forming reaction of N-confused oxoporphyrin and 2-aminopyridine derivatives. The chimera molecule enhances the intrinsic NH tautomerism of NCP to enable four possible tautomeric structures, three of which were identified by metal coordination.
通过N-杂氧卟啉与2-氨基吡啶衍生物的席夫碱形成反应，合成了一种带有外部氮杂二吡咯样配位位点的新型N-杂卟啉（NCP）类似物。这种嵌合分子增强了NCP固有的NH互变异构，从而产生四种可能的互变异构结构，其中三种通过金属配位得以确定。
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