Wojaczyński Jacek, Maciołek Justyna, Chmielewski Piotr J
Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50383, Wrocław, Poland.
Chem Asian J. 2017 Mar 16;12(6):643-647. doi: 10.1002/asia.201700129. Epub 2017 Feb 16.
A fully conjugated system 4 consisting of two 2-aza-21-carbaporphyrin (NCP) subunits bridged by dipyrrin was synthesized by a highly selective condensation of 3-pyrrole-NCP 2 with aryl aldehydes. The free base 4 as well as its silver(III) complex 5 exhibited flexibility of the bridge allowing synergetic binding of Ag , thus leading to a mixed-valence tetraporphyrinic assembly consisting of eight silver atoms which was characterized both in the solid state and in solution. Binding of chiral acid by 4 and 5 was shown by observation of an induced optical activity of the adducts.
通过3-吡咯-N-碳杂卟啉2与芳基醛的高度选择性缩合反应，合成了一种由二吡咯桥联两个2-氮杂-21-碳杂卟啉（NCP）亚基组成的完全共轭体系4。游离碱4及其银（III）配合物5表现出桥联的灵活性，允许银协同结合，从而形成由八个银原子组成的混合价四卟啉组装体，该组装体在固态和溶液中均得到了表征。通过观察加合物的诱导光学活性，表明4和5对手性酸具有结合作用。
