Emission behaviors of nitro- and oxy-polycyclic aromatic hydrocarbons during pyrolytic disposal of electronic wastes.

Emission factors (EFs) of polycyclic aromatic hydrocarbon (PAH) derivatives (12 nitro-PAHs and 4 oxy-PAHs) during the pyrolysis of two types of electronic waste (E-waste) were measured. Compositional profile, particle size distribution, gas-particle partitioning, correlations with precursor species and influences of pyrolytic temperature were investigated. The derivative products were dominated by oxy-PAHs. The averaged EFs of oxy-PAHs were 3.37 ± 4.10 μg/g and 32.6 ± 18.1 μg/g for PWBs and plastic casings, respectively, and those of nitro-PAHs were 85.7 ± 92.4 ng/g and 83.3 ± 69.7 ng/g, respectively. Most EFs of derivative species significantly correlated with their corresponding parent PAHs (p < 0.05), except a few cases, indicating formation of derivatives via related reactions of parent species. Most nitro-PAHs occurred in fine particles with the size < 2.1 μm, and oxy-PAHs were prevailing in fine particles with the size between 0.4 μm and 2.1 μm. Proportions of oxy-PAHs in particulate phase, especially those with higher molecular weight, were noticeably greater than those of the corresponding parent species. Below 480 °C, there was no evident difference in the EFs of PAH derivatives, while the EFs noticeably increased from 520 °C. With the increasing temperature, the majority of oxy-PAHs still occurred on finer particles, while the contribution of coarser particles tended to increase.