Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing 100048, China.
Department of Food Science and Human Nutrition, University of Illinois at Urbana-Champaign, 1302 West Pennsylvania Avenue, Urbana, IL 61801, USA.
Food Chem. 2019 Jun 1;282:153-163. doi: 10.1016/j.foodchem.2018.12.112. Epub 2019 Jan 3.
Toona sinensis (A. Juss.) M. Roem. (TS) possesses a unique and pleasant flavor and is consumed as a popular seasonal vegetable in certain parts of eastern and southeastern Asia. The potent odorants in raw and cooked TS were identified by combined sensory and instrumental analysis techniques, including sensory descriptive aroma profiling and two complimentary volatile isolation methods combined with gas chromatography-olfactometry (GC-O) techniques. Highly volatile odorants were determined by static headspace dilution analysis (SHDA)-GC-O, while those of intermediate- and semi-volatility were determined by solvent-assisted flavor evaporation-aroma extract dilution analysis (SAFE-AEDA). Among the numerous odorants identified by SHDA and SAFE-AEDA, (E,E)-bis-(1-propenyl) disulfide was found to be predominant in both raw and cooked TS. In agreement with results of sensory descriptive analysis, hexanal, (Z)-3-hexenal, (E)-2-hexenal and (Z)-3-hexen-1-ol contributed green, grassy and leafy aroma notes; while hydrogen sulfide, methyl thiirane, (E,E)-bis-(1-propenyl) disulfide and (E,Z)-bis-(1-propenyl) disulfide contributed pungent, sulfurous and alliaceous notes in TS.
香椿(Toona sinensis (A. Juss.) M. Roem.)具有独特而宜人的风味,是东亚和东南亚部分地区的一种受欢迎的时令蔬菜。采用感官描述分析和两种互补的挥发性物质分离方法结合气相色谱-嗅觉测量(GC-O)技术,对生香椿和熟香椿的强烈气味物质进行了鉴定。采用静态顶空稀释分析(SHDA)-GC-O 法确定高挥发性气味物质,采用溶剂辅助风味蒸发-香气提取稀释分析(SAFE-AEDA)法确定中挥发性和半挥发性气味物质。通过 SHDA 和 SAFE-AEDA 鉴定出的众多气味物质中,(E,E)-双-(1-丙烯基)二硫化物在生香椿和熟香椿中均占主导地位。与感官描述分析的结果一致,己醛、(Z)-3-己烯醛、(E)-2-己烯醛和(Z)-3-己烯-1-醇赋予了香椿生青、草香和叶香特征;而硫化氢、甲基噻烷、(E,E)-双-(1-丙烯基)二硫化物和(E,Z)-双-(1-丙烯基)二硫化物则赋予了香椿刺鼻、硫磺和大蒜样气味特征。