School of Microelectronics, School of Electronics and Information Engineering, Xi'an Jiaotong University, Xi'an 710049, China.
Science and Technology on Analog Integrated Circuit Laboratory, Chongqing 401332, China.
Sensors (Basel). 2019 Feb 1;19(3):625. doi: 10.3390/s19030625.
Oxygen plasma treatment has been reported as an effective way of improving the response of graphene gas sensors. In this work, a gas sensor based on a composite graphene channel with a layer of pristine graphene (G) at the bottom and an oxygen plasma-treated graphene (OP-G) as a covering layer was reported. The OP-G on top provided oxygen functional groups and serves as the gas molecule grippers, while the as-grown graphene beneath serves as a fast carrier transport path. Thus, the composite channel (OP-G/G) demonstrated significantly improved response in NH₃ gas sensing tests compared with the pristine G channel. Moreover, the OP-G/G channel showed faster response and recovering process than the OP-G channel. Since this kind of composite channel is fabricated from chemical vapor deposited graphene and patterned with standard photolithography, the device dimension was much smaller than a gas sensor fabricated from reduced graphene oxide and it is favorable for the integration of a large number of sensing units.
氧气等离子体处理已被报道为一种提高石墨烯气体传感器响应的有效方法。在这项工作中,报道了一种基于复合石墨烯沟道的气体传感器,该沟道底部有一层原始石墨烯(G),顶部有一层经过氧气等离子体处理的石墨烯(OP-G)作为覆盖层。顶部的 OP-G 提供了氧官能团,作为气体分子的抓手,而下面生长的石墨烯则作为快速载流子输运路径。因此,与原始 G 沟道相比,复合沟道(OP-G/G)在氨气气体传感测试中表现出显著改善的响应。此外,OP-G/G 沟道的响应和恢复过程比 OP-G 沟道更快。由于这种复合沟道是由化学气相沉积的石墨烯制成,并采用标准光刻技术进行图案化,因此器件尺寸比由还原氧化石墨烯制成的气体传感器小得多,有利于集成大量的传感单元。