State Key Laboratory on Integrated Optoelectronics, and College of Electronic Science and Engineering , Jilin University , Changchun 130012 , China.
ACS Appl Mater Interfaces. 2019 Feb 27;11(8):8210-8216. doi: 10.1021/acsami.8b19317. Epub 2019 Feb 15.
For data security applications, the use of fluorescent inks has become the most promising approach because of their convenience and low cost. However, traditional fluorescent inks are usually visible either under ambient light or UV light, whereas the improved stimuli-responsive inks are restricted to a single color. For the first time, full-color stimuli-responsive inks for information coding, encryption, and decryption are reported, which rely on the facile preparation and conversion of perovskite quantum dots. The information printed by the halide salt solution is invisible under ambient and UV light but becomes readable under UV light after spraying a unique developer. Besides, the primitive information can be stored for many years, even decades. Even after the decryption process, it still can be stored for at least several weeks. Most importantly, using butyl amine and acetic acid as encryption and decryption reagents, respectively, can switch off/on the luminescence. In this way, the printed information can be encrypted and decrypted, which shows great potential for information security applications.
对于数据安全应用,荧光墨水的使用由于其便利性和低成本已成为最有前途的方法。然而,传统的荧光墨水通常在环境光或紫外光下可见,而改进的刺激响应墨水则限于单一颜色。首次报道了全彩色刺激响应墨水用于信息编码、加密和解密,该墨水依赖于钙钛矿量子点的简便制备和转化。卤化物盐溶液印刷的信息在环境光和紫外光下不可见,但在喷涂独特的显影剂后可以在紫外光下读取。此外,原始信息可以保存多年,甚至几十年。即使在解密过程之后,它仍然可以保存至少几个星期。最重要的是,分别使用丁胺和乙酸作为加密和解密试剂,可以关闭/开启发光。通过这种方式,可以对打印信息进行加密和解密,这为信息安全应用展示了巨大的潜力。