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蒙脱土接枝聚丙烯酸复合的制备及其对水溶液中镧离子的吸附性能研究。

Preparation of montmorillonite grafted polyacrylic acid composite and study on its adsorption properties of lanthanum ions from aqueous solution.

机构信息

Engineering Research Center of Nano-Geomaterials of Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, 388 Lumo Road, Wuhan, 430074, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2019 Apr;26(10):9861-9875. doi: 10.1007/s11356-019-04422-9. Epub 2019 Feb 8.

Abstract

Montmorillonite grafted polyacrylic acid composite (GNM) was prepared by using ultraviolet radiation grafting method in this work. The synthesized materials were characterized by XRF, SEM, FTIR, XRD, TG, and XPS. The experimental equilibrium data indicates that the adsorbent is suitable for the Langmuir model and belongs to the pseudo-second-order kinetic model. The entire adsorption process is spontaneous, endothermic, and chaotically enhanced by thermodynamic analysis. The maximum adsorption capacity of La(III) by GNM was 280.54 mg/g at 313.15 K. In addition, the regeneration experiment shows that the adsorbent has good reusability and stable desorption efficiency. This study demonstrates that GNM has high adsorption performance and La(III) adsorption and regeneration capabilities to solve the water pollution caused by rare earth ions and regeneration capabilities for La(III).

摘要

本工作采用紫外辐射接枝法制备了蒙脱土接枝聚丙烯酸复合(GNM)。采用 XRF、SEM、FTIR、XRD、TG 和 XPS 对合成材料进行了表征。实验平衡数据表明,吸附剂适合 Langmuir 模型,属于准二级动力学模型。热力学分析表明,整个吸附过程是自发的、吸热的和混乱增强的。在 313.15 K 时,GNM 对 La(III)的最大吸附容量为 280.54 mg/g。此外,再生实验表明,该吸附剂具有良好的可重复使用性和稳定的解吸效率。本研究表明,GNM 具有高吸附性能和 La(III)吸附和再生能力,可解决由稀土离子引起的水污染问题,并具有 La(III)的再生能力。

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