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激光熔覆沉积制备的WNbMoTa难熔高熵合金

WNbMoTa Refractory High-Entropy Alloys Fabricated by Laser Cladding Deposition.

作者信息

Li Qingyu, Zhang Hang, Li Dichen, Chen Zihao, Huang Sheng, Lu Zhongliang, Yan Haoqi

机构信息

State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University, Xi'an 710049, China.

School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an 710049, China.

出版信息

Materials (Basel). 2019 Feb 11;12(3):533. doi: 10.3390/ma12030533.

Abstract

WNbMoTa refractory high-entropy alloys with four different tungsten concentrations ( = 0, 0.16, 0.33, 0.53) were fabricated by laser cladding deposition. The crystal structures of WNbMoTa alloys are all a single-phase solid solution of the body-centered cubic (BCC) structure. The size of the grains and dendrites are 20 μm and 4 μm on average, due to the rapid solidification characteristics of the laser cladding deposition. These are much smaller sizes than refractory high-entropy alloys fabricated by vacuum arc melting. In terms of integrated mechanical properties, the increase of the tungsten concentration of WNbMoTa has led to four results of the Vickers microhardness, i.e., = 459.2 ± 9.7, 476.0 ± 12.9, 485.3 ± 8.7, and 497.6 ± 5.6. As a result, NbMoTa alloy shows a yield strength (σ) and compressive strain (ε) of 530 Mpa and 8.5% at 1000 °C, leading to better results than traditional refractory alloys such as T-111, C103, and Nb-1Zr, which are commonly used in the aerospace industry.

摘要

通过激光熔覆沉积制备了四种不同钨浓度(= 0、0.16、0.33、0.53)的WNbMoTa难熔高熵合金。WNbMoTa合金的晶体结构均为体心立方(BCC)结构的单相固溶体。由于激光熔覆沉积的快速凝固特性,晶粒和枝晶的平均尺寸分别为20μm和4μm。这些尺寸比通过真空电弧熔炼制备的难熔高熵合金小得多。在综合力学性能方面,WNbMoTa中钨浓度的增加导致维氏显微硬度出现了四个结果,即= 459.2±9.7、476.0±12.9、485.3±8.7和497.6±5.6。结果表明,NbMoTa合金在1000°C时的屈服强度(σ)和压缩应变(ε)分别为530 Mpa和8.5%,比航空航天工业中常用的传统难熔合金如T-111、C103和Nb-1Zr的性能更好。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/87ef/6385082/4a28f342f4d2/materials-12-00533-g001.jpg

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