Chattopadhyay Taraknath, B S Anju, Gupta Shourya, S Ananya, Bertke Jeffery A, Kundu Subrata
School of Chemistry, Indian Institute of Science Education and Research, Thiruvananthapuram, Kerala 695551, India.
Dalton Trans. 2019 May 28;48(21):7085-7089. doi: 10.1039/c8dt04971h.
Nitrate and nitrite anions have multifaceted impacts on the environment and human health. We herein report selective recognition of nitrite over nitrate anion inside the cavity of bimetallic azacryptates having p-xylyl spacers. This work reveals a number of binding interactions which play pivotal roles in nitrite anion recognition by rigid metal cryptates.
硝酸根和亚硝酸根阴离子对环境和人类健康有着多方面的影响。我们在此报告了在具有对二甲苯间隔基的双金属氮杂穴合物腔内对亚硝酸根相对于硝酸根阴离子的选择性识别。这项工作揭示了许多在刚性金属穴合物识别亚硝酸根阴离子过程中起关键作用的结合相互作用。
