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基于氧化石墨烯和功能化碳纳米管的半开放式多孔网络用于吸声。

A graphene oxide and functionalized carbon nanotube based semi-open cellular network for sound absorption.

机构信息

The State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China.

出版信息

Soft Matter. 2019 Mar 6;15(10):2269-2276. doi: 10.1039/c8sm01326h.

Abstract

Noise pollution has been recognized as one of the leading environmental problems worldwide and has a negative impact on the physiological and psychological health of humans. Various porous polymeric materials have been found to be inefficient for sound absorption, especially in low-frequency interval; in addition, these materials have other disadvantages such as hygroscopicity and flammability. Herein, an efficient and economical semi-open cellular structure consisting of tiny self-assembled graphene oxide (GO) sheets interrupted by functionalized carbon nanotubes (CNT) was demonstrated as an acoustic composite foam. This innovative composite foam exhibits an approximately 100% and 20% enhancement over a band gap between 250 and 1600 Hz as compared to the pure melamine foam and graphene oxide-incorporated melamine foam with a thickness of 20 mm, respectively. The semi-open cellular structure results in optimal air-flow resistance, tortuosity against sound wave propagation, smaller viscous characteristic lengths, internal reflection and interfacial damping; hence, the composite foam shows advanced energy exhaustion and improved acoustic absorption. Furthermore, the inclusion of GO and CNT provides other properties including moisture insulation and fire retardancy. This kind of innovative sound absorbing material is inexpensive, easy to synthesize and environmentally friendly for commercial and industrial applications.

摘要

噪声污染已被认为是全球主要的环境问题之一,对人类的生理和心理健康有负面影响。各种多孔聚合物材料已被发现对于声音吸收效率低下,尤其是在低频区间;此外,这些材料还有其他缺点,如吸湿性和可燃性。在此,展示了一种高效且经济的半开放式多孔结构,该结构由微小的自组装氧化石墨烯 (GO) 片组成,其间穿插有官能化的碳纳米管 (CNT),作为声学复合泡沫。与 20mm 厚的纯三聚氰胺泡沫和掺入氧化石墨烯的三聚氰胺泡沫相比,这种创新的复合泡沫在 250 至 1600Hz 的带宽间隙中分别提高了约 100%和 20%。半开放式多孔结构导致了最佳的气流阻力、对声波传播的曲折度、更小的粘性特征长度、内部反射和界面阻尼;因此,复合泡沫表现出了先进的能量耗散和改善的吸声性能。此外,GO 和 CNT 的加入提供了包括防潮和阻燃在内的其他性能。这种创新的吸声材料价格低廉,易于合成,对商业和工业应用具有环保效益。

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