One-step preparation of molybdenum disulfide/graphene nano-catalysts through a simple co-exfoliation method for high-performance electrocatalytic hydrogen evolution reaction.

HYPOTHESIS

Recently, molybdenum disulfide (MoS) as a new type of catalyst, has been used for hydrogen evolution. In order to overcome the shortcomings of MoS, such as poor conductivity and lack of catalytic activity sites, various materials were added to prepare composites, such as graphene with good conductivity.

EXPERIMENTS

In this work, we combined MoS with graphene through a very simple liquid-phase salt-assisted co-exfoliation method. The obtained MoS/graphene nano-composites have been further applied to electrocatalyst of hydrogen evolution reaction. The influences of different ratio of MoS to graphene and different solvents of exfoliation on the electrocatalytic activity for the hydrogen evolution reaction have been investigated in detail.

FINDINGS

In general, the obtained MoS/graphene nano-catalysts exhibits the smallest Tafel slope of 61 mV/dec with the exfoliation solvent of isopropanol, and 65 mV/dec in N-methyl pyrrolidone. All the MoS/graphene composites exhibit much better catalytic activity than either MoS or graphene single substance due to the synergetic effect between MoS and graphene nanosheets.