Universal scaling of polygonal desiccation crack patterns.

Polygonal desiccation crack patterns are commonly observed in natural systems. Despite their quotidian nature, it is unclear whether similar crack patterns which span orders of magnitude in length scales share the same underlying physics. In thin films, the characteristic length of polygonal cracks is known to monotonically increase with the film thickness; however, existing theories that consider the mechanical, thermodynamic, hydrodynamic, and statistical properties of cracking often lead to contradictory predictions. Here we experimentally investigate polygonal cracks in drying suspensions of micron-sized particles by varying film thickness, boundary adhesion, packing fraction, and solvent. Although polygonal cracks were observed in most systems above a critical film thickness, in cornstarch-water mixtures, multiscale crack patterns were observed due to two distinct desiccation mechanisms. Large-scale, primary polygons initially form due to capillary-induced film shrinkage, whereas small-scale, secondary polygons appear later due to the deswelling of the hygroscopic particles. In addition, we find that the characteristic area of the polygonal cracks, A_{p}, obeys a universal power law, A_{p}=αh^{4/3}, where h is the film thickness. By quantitatively linking α with the material properties during crack formation, we provide a robust framework for understanding multiscale polygonal crack patterns from microscopic to geologic scales.