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一种用于低碳波特兰水泥的新型负碳沉淀碳酸钙外加剂(PCC-A)。

A New, Carbon-Negative Precipitated Calcium Carbonate Admixture (PCC-A) for Low Carbon Portland Cements.

作者信息

McDonald Lewis, Glasser Fredrik P, Imbabi Mohammed S

机构信息

School of Engineering, University of Aberdeen, Aberdeen AB24 3UE, UK.

Carbon Capture Machine (UK) Limited, Aberdeen AB10 1YL, UK.

出版信息

Materials (Basel). 2019 Feb 13;12(4):554. doi: 10.3390/ma12040554.

Abstract

The production of Portland cement accounts for approximately 7% of global anthropogenic CO₂ emissions. Carbon CAPture and CONversion (CAPCON) technology under development by the authors allows for new methods to be developed to offset these emissions. Carbon-negative Precipitated Calcium Carbonate (PCC), produced from CO₂ emissions, can be used as a means of offsetting the carbon footprint of cement production while potentially providing benefits to cement hydration, workability, durability and strength. In this paper, we present preliminary test results obtained for the mechanical and chemical properties of a new class of PCC blended Portland cements. These initial findings have shown that these cements behave differently from commonly used Portland cement and Portland limestone cement, which have been well documented to improve workability and the rate of hydration. The strength of blended Portland cements incorporating carbon-negative PCC Admixture (PCC-A) has been found to exceed that of the reference baseline-Ordinary Portland Cement (OPC). The reduction of the cement clinker factor, when using carbon-negative PCC-A, and the observed increase in compressive strength and the associated reduction in member size can reduce the carbon footprint of blended Portland cements by more than 25%.

摘要

波特兰水泥的生产约占全球人为二氧化碳排放量的7%。作者正在开发的碳捕获与转化(CAPCON)技术能够开发新方法来抵消这些排放。利用二氧化碳排放生产的负碳沉淀碳酸钙(PCC),可作为抵消水泥生产碳足迹的一种方式,同时可能对水泥水化、工作性、耐久性和强度有益。在本文中,我们展示了一类新型PCC混合波特兰水泥的力学和化学性能的初步测试结果。这些初步研究结果表明,这些水泥的性能与常用的波特兰水泥和波特兰石灰石水泥不同,后者已被充分证明可改善工作性和水化速率。已发现掺入负碳PCC外加剂(PCC-A)的混合波特兰水泥的强度超过了参考基准普通波特兰水泥(OPC)。使用负碳PCC-A时水泥熟料系数的降低,以及观察到的抗压强度增加和构件尺寸减小,可使混合波特兰水泥的碳足迹减少超过25%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c79b/6416591/d3afc04fcce7/materials-12-00554-g001.jpg

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