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发光席夫碱镧系单分子磁体:光学与磁学性质之间的关联

Luminescent Schiff-Base Lanthanide Single-Molecule Magnets: The Association Between Optical and Magnetic Properties.

作者信息

Long Jérôme

机构信息

Institut Charles Gerhardt, Equipe Ingénierie Moléculaire et Nano-Objets, Université de Montpellier, ENSCM, CNRS, Montpellier, France.

出版信息

Front Chem. 2019 Feb 6;7:63. doi: 10.3389/fchem.2019.00063. eCollection 2019.

DOI:10.3389/fchem.2019.00063
PMID:30788341
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6373491/
Abstract

Luminescent Single-Molecule Magnets (SMM) belong to a new class of multifunctional molecule-materials that associate luminescence and slow relaxation of their magnetization within a single crystalline phase. We present in this mini-review the major advances that have been achieved in this new field over the last few years. More particularly, we will focus on the use of Schiff-base complexes in order to correlate magnetism and luminescence, as well as discussing the future outlooks of the field.

摘要

发光单分子磁体(SMM)属于一类新型多功能分子材料,这类材料在单晶相中兼具发光特性和缓慢的磁化弛豫特性。在这篇综述中,我们介绍了过去几年在这个新领域所取得的主要进展。更具体地说,我们将重点关注席夫碱配合物在关联磁性和发光方面的应用,同时也会探讨该领域的未来展望。

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Chemistry. 2019 Jan 7;25(2):474-478. doi: 10.1002/chem.201804429. Epub 2018 Dec 6.
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Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet.在镝金属茂单分子磁体中,磁滞现象高达 80 开尔文。
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