Martínez-Abadía Marta, Antonicelli Gabriella, Saeki Akinori, Melle-Franco Manuel, Mateo-Alonso Aurelio
POLYMAT , University of the Basque Country UPV/EHU , Avenida de Tolosa 72 , E-20018 Donostia-San Sebastian , Spain.
Department of Applied Chemistry, Graduate School of Engineering , Osaka University , Suita , Osaka 565-0871 , Japan.
J Org Chem. 2019 Mar 15;84(6):3270-3274. doi: 10.1021/acs.joc.8b03207. Epub 2019 Mar 7.
The synthesis and optical, electrochemical, thermal, and electrical characterization of a new and unexpected 1- n-octyloxyperopyrene is reported. The structure of 1- n-octyloxyperopyrene has been unambiguously established by single-crystal X-ray diffraction. The solubility of this polycyclic aromatic hydrocarbon, endowed by the alkoxy substituent, allows the fabrication of thin-film field-effect transistors by liquid deposition methods. These devices show hole mobilities up to 1.61 × 10 cm V s.
报道了一种新型且出人意料的1-正辛氧基苝的合成及其光学、电化学、热学和电学表征。1-正辛氧基苝的结构已通过单晶X射线衍射明确确定。这种由烷氧基取代基赋予溶解性的多环芳烃，使得通过液相沉积法制造薄膜场效应晶体管成为可能。这些器件的空穴迁移率高达1.61×10 cm²V⁻¹s⁻¹ 。 （注：原文中“1.61 × 10 cm V s”表述有误，推测正确应为“1.61 × 10 cm²V⁻¹s⁻¹” ）
