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含异氰酸酯和环氧物质再生体系的老化SBS改性沥青的物理和流变性能评估

Assessment on Physical and Rheological Properties of Aged SBS Modified Bitumen Containing Rejuvenating Systems of Isocyanate and Epoxy Substances.

作者信息

Li Zhelun, Xu Xiong, Yu Jianying, Wu Shaopeng

机构信息

State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China.

School of Civil Engineering and Architecture, Wuhan Institute of Technology, Wuhan 430074, China.

出版信息

Materials (Basel). 2019 Feb 19;12(4):618. doi: 10.3390/ma12040618.

Abstract

Styrene⁻butadiene copolymer (SBS)-modified bitumen (SMB) is widely applied in pavement construction. With yearly services, many SMB wastes urgently need to be reclaimed for repaving roads based on the objectives of environmental protection, landfill saving, as well as resource utilization. The present work is focused on the investigation of the physical and rheological properties of aged SMB incorporated with rejuvenating systems consisting of fluid catalytic cracking slurry (FCC slurry), C12⁻14 aliphatic glycidyl ether (AGE), diphenylmethane diisocyanate (MDI), and other additives. The rejuvenating systems containing the main components of 10% FCC slurry, 10%FCC/3%AGE, and 10%FCC/3%AGE/1% MDI were respectively recorded as R, R, and R. The results indicate that both R and R have obvious workability that make contributions for improving comprehensive physical properties while slightly reducing the softening point, which were also proven to be effective for the re-rejuvenation of re-aged binder. The higher viscous-elastic temperature caused by the agglomeration of binder molecules in aged SMB could be dropped to a lower value with rejuvenating systems, while improving the low-temperature crack resistance. With the use of the R and R rejuvenating systems, the high-temperature deformation resistance of aged SMB fell, approaching the performance of fresh SMB. Vibration noise consumption could be improved for aged SMB incorporated with R and R in the form of viscous loss, while the effects for re-aged SMB containing the same rejuvenating systems were weakened but still effective.

摘要

苯乙烯-丁二烯共聚物(SBS)改性沥青(SMB)广泛应用于路面施工。随着逐年使用,许多SMB废料迫切需要回收,以便基于环境保护、节省填埋空间以及资源利用的目标重新铺设道路。目前的工作重点是研究老化的SMB与由流化催化裂化浆液(FCC浆液)、C12-14脂肪族缩水甘油醚(AGE)、二苯基甲烷二异氰酸酯(MDI)和其他添加剂组成的再生体系混合后的物理和流变性能。分别含有10%FCC浆液、10%FCC/3%AGE和10%FCC/3%AGE/1%MDI主要成分的再生体系分别记为R、R和R。结果表明,R和R都具有明显的施工性能,有助于改善综合物理性能,同时略微降低软化点,这也被证明对再老化粘结剂的再再生有效。老化的SMB中粘结剂分子团聚导致的较高粘弹性温度可通过再生体系降至较低值,同时提高低温抗裂性。使用R和R再生体系后,老化SMB的高温抗变形能力下降,接近新鲜SMB的性能。对于掺有R和R的老化SMB,以粘性损失的形式可以提高振动噪声消耗,而对于含有相同再生体系的再老化SMB,其效果减弱但仍然有效。

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