有机盐和 Merrifield 树脂负载的[PMO]（M = Mo 或 W）作为合成己二酸的催化剂。
Organic Salts and Merrifield Resin Supported [PMO] (M = Mo or W) as Catalysts for Adipic Acid Synthesis.
机构信息
Centre National de la Recherche Scientifique (CNRS), Laboratoire de Chimie de Coordination (LCC), Université de Toulouse, UPS, INPT, 205, route de Narbonne, 31077 Toulouse, France.
Université de Toulouse, IUT P. Sabatier, Département de Chimie, Av. G. Pompidou, BP 20258, 81104 Castres CEDEX, France.
出版信息
Molecules. 2019 Feb 21;24(4):783. doi: 10.3390/molecules24040783.
Adipic acid (AA) was obtained by catalyzed oxidation of cyclohexene, epoxycyclohexane, or cyclohexanediol under organic solvent-free conditions using aqueous hydrogen peroxide (30%) as an oxidizing agent and molybdenum- or tungsten-based Keggin polyoxometalates (POMs) surrounded by organic cations or ionically supported on functionalized Merrifield resins. Operating under these environmentally friendly, greener conditions and with low catalyst loading (0.025% for the molecular salts and 0.001⁻0.007% for the supported POMs), AA could be produced in interesting yields.
己二酸（AA）是通过在无有机溶剂条件下，使用 30%过氧化氢水溶液作为氧化剂，催化氧化环己烯、环氧环己烷或环己烷二醇，得到的。所使用的催化剂为多金属氧酸盐（POMs），其由有机阳离子包围或离子负载在功能化的 Merrifield 树脂上。在这些环保、更绿色的条件下，以及低催化剂负载量（分子盐为 0.025%，负载型 POM 为 0.001⁻0.007%）下，己二酸可以以有趣的产率得到。
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